Aquabis(2-amino-1,3-thiazole-4-acetato-κ2 O,N 3)nickel(II)
نویسندگان
چکیده
In the crystal structure of the title compound, [Ni(C(5)H(5)N(2)O(2)S)(2)(H(2)O)], the Ni(II) cation is located on a twofold rotation axis and chelated by two 2-amino-1,3-thia-zole-4-acetate (ata) anions in the basal coordination plane; a water mol-ecule located on the same twofold rotation axis completes the distorted square-pyramidal coordination geometry. Inter-molecular O-H⋯O and N-H⋯O hydrogen bonding, as well as π-π stacking between parallel thia-zole rings [centroid-centroid distance 3.531 (8) Å], helps to stabilize the crystal structure.
منابع مشابه
Tetraaqua(2,2′-diamino-4,4′-bi-1,3-thiazole-κ2 N 3,N 3′)nickel(II) bis(pyridine-2,6-dicarboxylato-κ3 O 2,N,O 6)nickel(II) trihydrate
The crystal structure of the title compound, [Ni(C(6)H(6)N(4)S(2))(H(2)O)(4)][Ni(C(7)H(3)NO(4))(2)]·3H(2)O, consists of Ni(II) complex cations, Ni(II) complex anions and lattice water mol-ecules. The Ni(II) ions in both the complex cation and anion assume a distorted octa-hedral coordination geometry. O-H⋯O, N-H⋯O and C-H⋯S hydrogen bonds occur in the crystal structure.
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متن کاملBis(1H-benzimidazole-κN 3)bis[2-(naphthalen-1-yl)acetato-κ2 O,O′]nickel(II) monohydrate
In the title compound, [Ni(C(12)H(9)O(2))(2)(C(7)H(6)N(2))(2)]·H(2)O, The Ni(II) cation is located on a twofold rotation axis and is six-coordinated in a distorted NiN(2)O(4) octa-hedral geometry. The asymmetric unit consists of a nickel(II) ion, one 2-(naphthalen-1-yl)acetate anion, a neutral benzotriazole ligand and one half of a lattice water mol-ecule. The crystal packing is stabilized by O...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009